Linearizing Engineering Models
Many engineering laws are curves: tool life falls as a power of cutting speed, and reaction rates climb exponentially with temperature. Take logs and they turn into straight lines, which ordinary least squares can fit, and translating the slope and intercept back gives you the physical constants.
What the symbols mean
- Coefficient
The value of y at x = 1, recovered as e raised to the fitted intercept.
- Exponent
The slope on log–log axes: a 1% change in x changes y by about b%.
What the symbols mean
- Rate constant
How fast a reaction or a degradation runs at absolute temperature T.
- Activation energy
The energy barrier, in J/mol. The slope of ln k against 1/T is −Eₐ/R.
- Gas constant
8.314 J/(mol·K). With Eₐ in eV, use Boltzmann's constant 8.617 × 10⁻⁵ eV/K instead.
- Absolute temperature
In kelvin: °C + 273.15.
What the symbols mean
- Predicted log response
b₀ + b₁ ln x, the fitted line on the log scale.
- Residual SD on the log scale
The scatter about the fitted line in log units, roughly the relative scatter of y.
Explanation
Linearizing is simply rewriting a curved law so it becomes a straight line, then fitting that line with the regression you already know. Logs are the tool because they turn multiplication into addition and powers into multiplication: a power law becomes , and an exponential law becomes a line in . The only new step is translating back: the slope is the exponent (or the activation energy), and the intercept, un-logged, is the constant. It's a change of glasses, not a new method.
The scene. A machinist cuts steel at 150 m/min and the carbide insert lasts about 50 minutes; at 300 m/min it lasts 3. Doubling the speed cut tool life by a factor of 16. That's no line. It's Taylor's tool-life equation, , a power law, and a plot of the raw data curves hard while a plot of against is straight.
Why logs straighten these curves. Logs turn products into sums and powers into multiples:
- Power law : , a line on log–log axes with slope . Taylor's gives .
- Exponential : , a line on semi-log axes. Newton's law of cooling, , the solution of a first-order linear ODE, gives .
- Arrhenius : , a line in with slope .
You've met one of these already: the Weibull plot of against is a line with slope .
Fit, then transform back. Fit on (or on ) by least squares exactly as for a calibration curve, then undo the logs: ; for Taylor, and ; for Arrhenius, when the predictor is .
The error model changes too. Least squares on logs assumes constant scatter on the log scale, which means multiplicative error on the original scale: tool lives that vary about ±10% whether they're 3 minutes or 50. That's usually how such data behave, and it's why the fan-shaped residuals of the diagnostics lesson often disappear after a log. If the error really is additive, a log fit overweights the small values, so check the residual plot on the log scale.
Median, not mean. If is normal with mean and SD , then is the median of , and the mean is , a little larger (the lognormal mean). So predicts the typical life, with half failing sooner and half later. With the difference is under 0.1%; with it's 13%.
Arrhenius and accelerated testing. Parts run hot fail sooner, by the ratio of the rates. That ratio is the acceleration factor:
A life measured at the stress temperature, multiplied by , estimates the life in service, which feeds straight into the MTTF of the reliability lessons.
A common mistake. Temperatures usually come in °C, so it's tempting to plug them straight into . The Arrhenius law needs kelvin; with °C the line is wrong and so is the activation energy. Also watch for mixing and (the intercepts differ, so convert consistently), quoting as a mean, and extrapolating an Arrhenius line across a change of failure mechanism.
See it
Worked examples
Tool-life tests on a carbide insert: at cutting speeds m/min the inserts lasted min. Fit Taylor's equation .
- 1
Take logs: and .
For the epoxy fit with , find the activation energy and how much faster the adhesive cures at 80 °C than at 25 °C.
- 1
The slope in is K, and it equals , so J/mol kJ/mol.
Practice
Type your answer and check it. Solve them all to complete the lesson.
Fan power is expected to follow a power law in rotor speed, . Which plot of the test data should be a straight line?
A lithium cell's capacity-fade rate doubles when its storage temperature rises from 25 °C to 35 °C. Assuming Arrhenius behavior, estimate the activation energy in kJ/mol, to 3 significant figures ( J/(mol·K)).
Using the tool-life fit from the example, at what cutting speed will an insert last 30 minutes? (m/min, to 3 significant figures)
A steel casting cools in 25 °C air. Its temperature at and min is and °C. Newton's law of cooling says . Fit against by least squares and predict when the casting reaches 60 °C, in minutes to 3 significant figures.
A log-scale model predicts for a bearing at a given load (life in thousands of hours), with residual SD on the log scale. Estimate the median life and the mean life, in thousands of hours. Enter both.
A power transistor's dominant failure mechanism has activation energy eV. In a test at a junction temperature of 125 °C its MTTF is 1200 hours. Estimate the MTTF at 55 °C in thousands of hours, to 3 significant figures. (Boltzmann's constant is eV/K.)
Raw-scale residuals from a tool-life fit fan out (longer lives scatter more), but after fitting against the residuals form an even band. What does that say about the errors?
The hardest one here. Get it, and you've got this lesson.
An epoxy adhesive cures by a first-order reaction. Its rate constant (per hour) is at 300 K, at 320 K, at 340 K and at 360 K. Fit against by least squares, find in kJ/mol, and predict how long the adhesive needs to reach 90% cure at 40 °C, when , in hours. Enter and , to 3 significant figures.
Where it's used
Machining handbooks list Taylor constants fitted on log–log axes, and shops use them to set cutting speeds for planned tool changes. Electronics makers run accelerated life tests at high temperature and convert the results to field life with Arrhenius acceleration factors. Chemical engineers estimate activation energies from Arrhenius plots, and battery engineers fit calendar aging the same way. Fatigue (S–N) curves, pump and fan laws and creep rates are all power laws fitted after a log.